Download presentations for scientific and practical work indicators. Presentation - Research work “Natural indicators. Household tools analysis
MKOU Marshansk secondary school
Research in chemistry
"Indicators in our life".
The work was carried out by pupils of the 8th grade
Sidorova Larisa
Kuryshko Anastasia
Burmatova Svetlana
Head: Sinitsina Margarita
Anatolyevna - chemistry teacher
2016 year
Introduction
Indicators opening history
Classification of indicators.
Natural indicators
Experimental part.
Conclusion.
Bibliography.
1. Introduction
In nature, we meet with various substances that surround us. This year we began to get acquainted with an interesting subject - chemistry. How many substances are there in the world? What are they? Why do we need them and what benefits do they bring?
We were interested in substances such as indicators. What are indicators?
In the lessons when studying the topic "The most important classes of inorganic compounds" we used indicators such as litmus, phenolphthalein and methyl orange.
Indicators (from English indicate-to indicate) are substances that change their color depending on the environment of the solution. Using indicators, you can determine the environment of the solution
We decided to find out whether it is possible to use those natural materials that are at home as indicators.
Purpose of work:
Explore the concept of indicators;
Get acquainted with their opening and functions performed;
Learn to distinguish indicators from natural objects;
Investigate the effect of natural indicators in various environments;
Research methods :
Study of popular science literature;
Obtaining solutions of indicators and working with them
2. History of opening indicators
Indicators were first discovered in the 17th century by the English physicist and chemist Robert Boyle. Boyle conducted various experiments. One day, when he was doing another research, the gardener came in. He brought violets. Boyle loved flowers, but he needed to experiment. Boyle left the flowers on the table. When the scientist finished his experiment, he accidentally looked at the flowers, they were smoking. To save the flowers, he dipped them into a glass of water. And - what a miracle - violets, their dark purple petals, turned red. Boyle became interested and conducted experiments with solutions, each time adding violets and observing what happens to the flowers. In some of the glasses, the flowers immediately began to turn red. The scientist realized that the color of the violets depends on what kind of solution is in the glass, what substances are in the solution. The best results were obtained from experiments with litmus lichen. Boyle dipped ordinary paper strips into the infusion of litmus lichen. I waited until they were soaked in infusion, and then dried them. These tricky pieces of paper Robert Boyle called indicators, which in Latin means "pointer", as they indicate the environment of the solution. It was the indicators that helped the scientist discover a new acid - phosphoric, which he obtained by burning phosphorus and dissolving the resulting white product in water. Currently, the following indicators are widely used in practice: litmus, phenolphthalein, methyl orange.
2. Classification of school indicators and how to use them
Indicators have different classifications . One of the most common are acid-base indicators, which change color depending on the acidity of the solution. Nowadays, several hundred artificially synthesized acid-base indicators are known, some of them can be found in the school chemistry laboratory.
Phenolphthalein (sold in a pharmacy under the name "purgen") - fine crystalline powder, white or white with a slightly yellowish sheen. Let's dissolve in 95% alcohol, practically insoluble in water. Colorless phenolphthalein in an acidic and neutral medium is colorless, and in an alkaline medium it turns crimson. Therefore, phenolphthalein is used to determine the alkaline environment.
Methyl orange - orange crystalline powder. We will moderately dissolve in water, we will easily dissolve in hot water, practically insoluble in organic solvents. Color transition of the solution from red to yellow.
Lacmoid (litmus) - black powder. Let's dissolve in water, 95% alcohol, acetone, glacial acetic acid. Color transition from red to blue.
Indicators are usually used by adding a few drops of an aqueous or alcoholic solution, or a little powder to the test solution.
Another application is using strips of paper soaked in an indicator solution or indicator mixture and dried at room temperature. Such strips are produced in a wide variety of versions - with a color scale applied to them - a color standard or without it.
3. Natural indicators
Acid-base indicators are not only chemical. They are around us, but usually we don’t think about it. These are herbal indicators that can be used in everyday life. For example, the juice of beetroot in an acidic environment changes its ruby color to bright red, and in an alkaline environment - to yellow. Knowing the properties of beetroot juice, you can make the color of the borscht bright. To do this, add a little vinegar or citric acid to the borscht. If lemon juice is dropped into a glass of strong tea or a few crystals of citric acid are dissolved, the tea will immediately become lighter. If you dissolve baking soda in tea, the solution will darken.
Juices or decoctions of brightly colored fruits or other plant parts are most often used as natural indicators. Such solutions must be stored in dark containers. Unfortunately, natural indicators have a serious drawback: their decoctions quickly deteriorate - they turn sour or moldy (alcohol solutions are more stable). In this case, it is difficult or impossible to distinguish, for example, a neutral medium from a weakly acidic or slightly alkaline from a strongly alkaline one. Therefore, in chemical laboratories, synthetic indicators are used, which sharply change their color in rather narrow pH ranges.
experimental part
What indicators can be used at home? To answer this question, we examined solutions of juices of fruits and flowers of plants such as Kalanchoe (orange, red and white flowers), carrots, blue and yellow onions (husks and the bulb itself), tulip (red flowers and green leaves), geranium (flowers are pink and white), dandelion, pansies, black currants and raspberries (berries). We prepared solutions of the squeezed juices of these plants and fruits, since the solutions quickly deteriorate, we prepared them immediately before the experiment as follows: we ground some leaves, flowers or fruits in a mortar, then added a little water. The prepared solutions of natural indicators were examined with a solution of acid (hydrochloric acid) and alkali (sodium hydroxide). All solutions taken for research changed or did not change their color depending on the medium. The results of the studies obtained were entered in the table.
Object under study | Initial color of the solution in a neutral medium | Acid staining | Alkaline dyeing |
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Kalanchoe (orange flowers) | pale yellow | yellow | pale yellow |
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Kalanchoe (red flowers) | maroon | pink | emerald green |
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Kalanchoe (pink flowers) | lilac | pink | green |
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Tulip (flowers are red) | maroon | dark orange | yellow-green |
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Tulip (leaves) | light green | without changes | green |
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Blue onion (husk) | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Blue onion (bulb) | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Yellow onion (husk) | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Yellow onion (bulb) | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Carrots (juice) | orange | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Beetroot (juice) | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Dandelion | yellow-green | light yellow | dark yellow |
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Black currant berries | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Raspberries | |||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||||
Geranium (bright pink flowers) | hot pink | hot pink | light brown |
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Geranium (white flowers) | white | light yellow | white |
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Pansies (purple flowers) | violet | hot pink | emerald green |
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Pansies (yellow flowers with a brown center) | gray | bright green | Hot pink |
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Hibiscus |
Slide 1"Natural Indicators" RESEARCH WORK Slide 2CONTENT Slide 31. Introduction Slide 41. Introduction Slide 52.1. From the history of indicators Slide 62.1. Classification of indicators Slide 72.2 Natural indicators Slide 82.2 Biochemical role of indicators Slide 92.2 Requirements for indicators Slide 103.1. Own research Slide 113.2. Results of the study of indicator plants TABLE 1: Slide 123.3. Determination of the medium of solutions of dishwashing detergents using vegetable indicators In biology lessons, I learned that the outer surface of the epidermis is covered with a microscopically thin layer - an acid mantle. Many biochemical processes take place in the epidermis. As a result, acids are formed - lactic, citric and others. Plus to this: sebum and sweat. All this constitutes the acidic mantle of the skin. Therefore, normal skin is acidic, with skin pH averaging 5.5. When using alkaline dishwashing detergents, we disrupt the normal acidic environment of the skin of the hands. To protect the skin of the hands from negative impact detergents for dishes should have a pH value corresponding to the pH value of the acid mantle of the epidermis. With the help of prepared solutions of natural indicators, I checked what kind of environment different dish detergents have. Slide 133.3. Reaction of the medium in dishwashing detergent solutions TABLE 2: Slide 144. Conclusion After my research work, I came to the following conclusions: - many natural plants have the properties of acid-base indicators, capable of changing their color depending on the environment in which they enter; - solutions of herbal indicators can be used, for example, as acid-base indicators for determining the medium of solutions of dishwashing detergents at home; - homemade indicators from natural raw materials can be used in chemistry lessons in schools, if there is a problem of providing the school with chemical reagents. According to the results of the study, the indicator properties of the objects under study were proved. Moreover, the following pattern is observed here - all these natural objects in an acidic environment are predominantly colored red, and in an alkaline environment - in green-yellow. And this proves that they do contain anthocyanins. This study showed that in nature there are such plant objects that change their color depending on the acidity of the environment. Therefore, we can call them natural indicators. Slide 151) Natural indicators can be used in chemistry lessons, elective courses. 2) Plant indicators can be used in everyday life. Beet juice in an acidic environment changes its ruby color to bright red, and in an alkaline environment - to yellow. Knowing the properties of beetroot juice, you can make the color of the borscht bright. To do this, add a little vinegar or citric acid to the borscht. 3) To determine the composition of drugs that are used for treatment, you can use natural indicators. Many medications are acids, salts and bases. Having studied their properties, you can protect yourself. For example, aspirin (acetylsalicylic acid), many vitamins should not be taken on an empty stomach, as the acids in their composition will damage the stomach lining. 4) The results of research work can be used to determine the pH (pH) of various solutions, for example, dairy products, broths, lemonade and others, as well as to determine the acidity of the soil, since on the same soil, depending on its acidity, one species plants can produce high yields, while others will be oppressed. 5) Detergents for dishes "Myth", "Fairy", "AOS" have an alkaline and slightly alkaline environment and when using them, rubber gloves must be used to protect the skin of the hands from negative effects, since the alkaline environment destroys the acid mantle of the epidermis; 6) In the poem of the famous English poet R.Kipling "Blue Roses", there are the following lines: Somehow, dear, I brought a whole heap of red roses. She did not take - and in tears, blue, find her roses. I shouldn't have traveled all over the world - there are no blue roses under the sun. Of course, there are no raspberry cornflowers and blue lilies of the valley, but you can give the flowers a fantastic color. Pour concentrated ammonia into a cylinder and place a red rose flower. After a few minutes, a color change can be observed. When interacting with vapors of ammonia, the color of the red rose turns blue. Slide 166. References 1.Alikberova L.Yu. Entertaining chemistry. - M .: AST-PRESS, 2002.2. Alikberova L.Yu. Entertaining chemistry. A book for students, teachers and parents. - M .: AST-PRESS, 1999.3. Oganesyan E.T. A guide to chemistry for university applicants. - M .: graduate School, 1998 4. Savina L.A. I get to know the world. Children's encyclopedia. Chemistry. - M .: AST, 1996. 5. New encyclopedic dictionary. - M .: Great Russian Encyclopedia. Rinol Classic, 2000. 6. Encyclopedic Dictionary of a Young Chemist. - M .: Pedagogika, 1982.7.Stepin B.D., Alikberova L.Yu. Entertaining tasks and spectacular chemistry experiments. - M .: Bustard, 2002.8. Internet resources. 9. Pilipenko A.T. "Handbook of Elementary Chemistry". Kiev "Naukova Dumka". 1973 Pages 164 -167. 10. Baykova V.M. "Chemistry after school". 1976 P. 90-95. 11. Scientific - practical journal "Chemistry for schoolchildren" No. 4 2007. p.60 12. Educational-methodical newspaper for teachers of chemistry "September 1", No. 22, 2007. 13. Balaev I.I. "Home experiment in chemistry." 14. Nazarova T.S., Grabetsky A.A. "Chemical experiment at school", Moscow. 1987 15. Information from the website alchemic.ru "Good advice". | Municipal educational institution "Secondary school No. 2 in Zhirnovsk" Volgograd region Research work in chemistry on the topic: "Indicators in our life" Completed: student 8 "A" class MOU "Secondary school No. 2 in Zhirnovsk" Danina Maria Vitalievna (14 years old) Head: chemistry teacher Anastasia Sergeevna Aleshkova Zhirnovsk, 2015 Introduction ………………………………………………………………… ..3 - 4
Conclusion ……………………………………………………………………… 14 References ………………………………………………………… ... 15 Introduction Nature is an amazing creation of the Universe. The natural world is beautiful, mysterious and complex. This world is rich in a variety of fauna and flora.The plant kingdom surprises us with its variety of color shades. The color palette is so varied that it is impossible to say how many flowers and their shades exist in the plant world. Thus, the question arises - what does the color of certain plants depend on? What is the structure of plants? What do they contain? And what are their properties? The further we plunge into the world of plants, the more and more we ask ourselves other questions. It turns out that the color of plants is determined by the chemical composition of the cellular content of each plant. Or rather, the so-called bioflavonoids are to blame. These are natural chemical compounds that give a certain color shade and properties to any plant. Therefore, there are many bioflavonoids. These include anthocyanins, xanthophylls, carotenoids, catechins, flavonols, flavonones, and others. The benefits of many plants are undeniable. Since ancient times, people have used plants as medicines... Therefore, it is not for nothing that folk medicine arose, based on the unique and medicinal properties of plants. Why we have chosen this topic. First, we are interested in the properties of plant objects. Second, what is their role in a science like chemistry? How are their indicator properties determined? And, thirdly, how you can use their properties for medicinal purposes. Therefore, we will consider flavonoids such as anthocyanins. Because they are ideal candidates for our research. Relevance of the topic lies in the fact that today more and more interest is in the properties of plant objects for their application and use in various fields of science, such as chemistry, biology and medicine. purpose of work: using research to prove the presence of natural indicators - anthocyanin pigments in plant objects and to study their properties. Research objectives: 1) Analyze literature on plant physiology and biochemistry of indicators 2) Explore natural objects for the presence of indicators - anthocyanins; 3) To prove the indicator properties of plant pigments - anthocyanins; 4) Reveal the significance and biochemical role of natural objects containing anthocyanins.
Chemical indicators include such as acid-base, universal, redox, adsorption, fluorescent, complexometric and others. Also, indicators can be found among natural objects. The pigments of many plants can change color depending on the acidity of the cell sap. Consequently, pigments are indicators that can be used to study the acidity of other solutions. The common name for such plant pigments is flavonoids. This group includes the so-called anthocyanins, which have good indicator properties. The most famous plant acid-base indicator used in chemistry is litmus. It was already known in Ancient Egypt and Ancient Rome, where it was used as a purple paint substitute for expensive purple. Litmus was prepared from special types of lichens. The crushed lichens were moistened, and then ash and soda were added to this mixture. The prepared mixture was placed in wooden barrels, urine was added and kept for a long time. Gradually the solution became dark blue. It was evaporated and used in this form for dyeing fabrics. Later litmus was discovered in 1663. It was an aqueous solution of lichen growing on rocks in Scotland. The following historical fact is also known: “In the laboratory of the famous English scientist physicist and chemist Robert Boyle, as usual, hard work was in full swing: candles were burning, various substances were heated in retorts. The gardener entered Boyle's study and placed a basket of deep purple violets in the corner. At this time, Boyle was going to conduct an experiment on the production of sulfuric acid. Fascinated by the beauty and aroma of violets, the scientist, taking a bunch with him, went to the laboratory. The lab technician told Boyle that two bottles of hydrochloric acid were delivered from Amsterdam yesterday. Boyle wanted to look at the acid, and to help the technician pour the acid, he put the violets on the table. Then, before heading to the office, he took his bouquet and noticed that the violets were slightly smoking from the spray of acid on them. To rinse the flowers, he dipped them into a glass of water. After a while, he glanced at the glass with violets, and a miracle happened: the dark purple violets turned red. Naturally, the scientist began research. He found that other acids also stain violet petals red. He thought that if he prepared an infusion from the petals and added it to the solution under study, he would be able to find out if it was sour or not. Boyle began to prepare infusions from other plants: medicinal herbs, tree bark, plant roots, etc. However, the most interesting was the purple infusion obtained from litmus lichen. Acids changed its color to red, and alkalis to blue. Boyle ordered to soak paper with this infusion and then dry it. This is how the first litmus paper was created, which is available in any chemical laboratory. Thus, one of the first substances was discovered, which Boyle already then called “ indicator. " Robert Boyle prepared an aqueous solution of litmus lichen for his experiments. The bottle in which he kept the infusion was needed for hydrochloric acid. After pouring out the infusion, Boyle filled a bottle with acid and was surprised to find that the acid turned red. Intrigued by this phenomenon, Boyle added a few drops to an aqueous solution of sodium hydroxide for a test and found that in an alkaline medium the litmus turns blue. So the first indicator for the detection of acids and alkalis was discovered, named after the lichen by the litmus. Since then, this indicator has been one of the indispensable indicators in various research in the field of chemistry. " Acid-base indicators. Most often, acid-base indicators are used in laboratories. These include phenolphthalein, litmus, methyl orange, bromothymol blue, and others. Acid-base indicators are organic compounds that can change color in solution when acidity changes. They change color within fairly narrow pH ranges. There are many such indicators, and each of them has its own field of application. Such indicators are among the most stable and in demand in chemistry laboratories.
The pigments of many plants can change color depending on the acidity of the cell sap. Therefore, plant pigments are indicators that can be used to study the acidity of other solutions. The general name for natural pigments is flavonoids. This group includes carotenoids, xanthophylls, anthocyanins, respectively, determining the yellow, orange, red, blue, purple color of plants. Anthocyanins are natural pigments from the flavonoid group. A large number of objects are known to be rich in anthocyanins. These are raspberries, strawberries, strawberries, cherries, plums, red cabbage, black grapes, beets, blueberries, blueberries, cranberries and many others. Anthocyanins give the fruits purple, blue, brown, red or orange colors. This variety is due to the fact that the color changes depending on the balance of acids and alkalis. The structure of anthocyanins was established in 1913 by the German biochemist R. Willstatter. The first chemical synthesis was carried out in 1928 by the English chemist R. Robinson. The variety of colors is explained not only by the peculiarities of their structure, but also by the formation of complexes with ionic K (purple salt), Mg and Ca (blue salt), as well as adsorption on polysaccharides. The formation of anthocyanins is favored by low temperatures and intense lighting. Anthocyanins have good indicator properties: in a neutral medium they acquire a purple color, in an acidic medium - a red color, in an alkaline medium - a green-yellow color. Indicators allow you to quickly and accurately monitor the composition of liquid media, monitor changes in their composition or the course of a chemical reaction. As already mentioned, the common name for all natural pigments, natural indicators, is flavonoids. Flavonoids are heterocyclic compounds. Depending on the structure and oxidation state, they are divided into anthocyanins, catechins, flavonols, flavonones, carotenoids, xanthophylls, etc. They are found in plants in a free state and in the form of glycosides (with the exception of catechins). Anthocyanins are bioflavonoids that give the fruit purple, blue, brown, red color. Entering the human body with fruits and vegetables, anthocyanins exhibit an effect similar to vitamin P; they maintain a normal state of blood pressure and blood vessels, preventing internal hemorrhages. Anthocyanins are required by brain cells, improve memory. Anthocyanins are powerful antioxidants that are 50 times stronger than vitamin C. Many studies have confirmed the benefits of anthocyanins for vision. The highest concentration of anthocyanins is found in blueberries. Therefore, preparations containing blueberries are most in demand in medicine. Since anthocyanins have good indicator properties, they can be used as indicators for identifying acidic, alkaline or neutral environments, both in chemistry and in everyday life.
Reagents: 1) water 2) 5% - hydrochloric acid 3) 5% sodium hydroxide Equipment and utensils: mortar, pestle, test tubes, pipette, tripod Study material: plant objects
Table 2.1 Change in the color of natural indicators in an acid - alkaline environment
As a result, we found that the color of plant pigments under the action of acids and alkalis changes depending on the type of plant and the color of the original pigments. For example, carotenoids in common carrots practically do not change color when acidity changes. And since the studied pigments of onion peel and lemon peel are very similar in color to the pigments of carrots and, like carrots, did not change color with a change in acidity, we can assume that their color is also due to carotenoids. Carotenoids are unsuitable as acid-base indicators. Plants containing anthocyanins changed their color under the action of acids and alkalis. For example, indoor violet, indoor geranium, Decembris, gerbera, beets discolored in an alkaline environment, and acquired a raspberry color in an acidic one. Ordinary tea can also be used at home as a natural indicator. Have you noticed that tea with lemon is much lighter than without lemon. In an acidic environment, it becomes discolored, and in an alkaline environment it becomes darker. conclusions
Conclusion As a result of this research work, we have proved that among natural objects there are a large number of natural indicators that can be used and applied both in everyday life and in chemistry for various other studies. Anthocyanins are also often used in medicine due to their unique properties. Anthocyanins are of immense biochemical importance. Anthocyanins are powerful antioxidants that neutralize free radicals, which in turn have a detrimental effect on our body. Thus, anthocyanins are guarantors of a long and healthy life cells, which means they extend our life as well. Many studies have confirmed the benefits of anthocyanins for vision. They also help lower blood sugar levels. This is especially true for those people who are sick with diabetes. To get all these benefits, scientists advise to eat only half a glass of blueberries a day - fresh or frozen. Therefore, preparations containing blueberries are most in demand in medicine. Bibliography:
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See similar
Raw materials for cooking indicator | Natural indicator color | Coloring in sour environment | Coloring in alkaline environment |
Raspberries | Brown | Brown | Dark brown |
Chokeberry berries | Red brown | Pale pink | Dark green |
Strawberries | Red-orange | Orange | Dark yellow |
Buckthorn bark | Dark yellow |
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Red cabbage | Blue violet | ||
Mallow petals | Dark green |
Conclusion
Bibliography
Internet resources.
Application
Buckthorn mallow flower
Chokeberry Raspberry
Strawberry Red cabbage
�PAGE � �PAGE �7�
In the world of indicators
Chemistry teacher, MOU "Satlamyshevskaya Secondary School"
Salakhova Gulina Faritovna
Introduction page 3
From the history of indicators p. 4
Classification of indicators page 5
Natural indicators p. 6
Methods of manufacturing indicators from natural raw materials p. 7
Determination of the environment of dishwashing detergents using
plant indicators p. 8
Conclusion p. 9
References p. 10
Appendix p. 11-12
Introduction
Indicators are organic and inorganic substances that change their color depending on the reaction of the environment. The name "indicators" comes from the Latin word indicator, which means "pointer".
In a chemical laboratory or at a factory, indicators in a visual form will tell you whether the chemical reaction has gone through to the end or not, it is enough to add one reagent to another, or you need to add more. (5)
When studying acids and bases in chemistry lessons, I learned that the juices of brightly colored berries, fruits and flowers have the properties of acid-base indicators, that is, they change their color when the acidity of the environment changes.
I was interested in the question: what plants can be used as indicators? Can you prepare herbal indicator solutions yourself? Are homemade indicators suitable for home use, for example, to determine the environment of dish detergents in order to detect their negative effects on the skin of the hands?
purpose of work: preparation of solutions of plant indicators from natural raw materials and determination with their help of the environment of solutions of detergents for dishes.
To achieve this goal, it is necessary to solve the following tasks:
Examine literary sources on the topic;
Consider the classification of indicators;
Prepare solutions of indicators from natural raw materials;
Conduct a study to determine the medium of solutions of dishwashing detergents.
Object of study: natural plants with indicator properties.
Subject of study: solutions of herbal indicators.
Hypothesis: solutions of herbal indicators can be prepared independently and used at home to determine the medium of solutions of dishwashing detergents.
From the history of indicators
The history of indicators begins in the 17th century. Back in 1640, botanists described heliotrope - a fragrant plant with dark purple flowers, from which the coloring matter was isolated. This dye, along with the juice of violets, has become widely used by chemists as an indicator. You can read about this in the works of the famous physicist and chemist of the 17th century Robert Boyle.
In 1663 litmus was discovered - an aqueous infusion of lichen growing on the rocks of Scotland. Robert Boyle prepared an aqueous infusion of litmus lichen for his experiments. The bottle in which he kept the infusion was needed for hydrochloric acid. After pouring out the infusion, Boyle filled a bottle with acid and was surprised to find that the acid turned red. Having become interested in this, Boyle added a few drops of litmus infusion to an aqueous solution of sodium hydroxide for testing and found that in an alkaline medium the litmus turns blue. This is how the first indicator for the detection of acids and bases was discovered, named after the lichen by the litmus. (1)
Phenolphthalein, which is used in the form of an alcohol solution, acquires a crimson color in an alkaline medium, and is colorless in a neutral and acidic medium. The synthesis of phenolphthalein was first carried out in 1871 by the German chemist Adolph von Bayer, the future Nobel Prize laureate. (5)
As for the methyl orange indicator, it is indeed orange in a neutral environment. In acids, its color becomes pink-raspberry, and in alkalis - yellow.
Nowadays, chemists often use indicator paper impregnated with a mixture of different indicators - a universal indicator.
Classification of indicators
Some of the most common - acid-base indicators, which change color depending on the acidity of the solution. This happens because indicator molecules have different structures in acidic and alkaline environments. An example is the well-known indicator phenolphthalein. In an acidic medium, this compound is in the form of undissociated molecules and the solution is colorless, and in an alkaline medium it is in the form of ions and the solution has a crimson color.
In addition to acid-base, other types of indicators are also used.
Redox indicators change their color depending on what is present in the solution of the oxidizing agent or reducing agent. Such indicators are substances that themselves undergo oxidation or reduction, and the oxidized and reduced forms have different colors. For example, the oxidized form of diphenylamine is violet in color, while the reduced form is colorless. (2)
Widespread complexometric indicators- substances that form colored complex compounds with metal ions.
Some substances are adsorbed on the surface of the sediment, changing its color; such indicators are called adsorptive.
When determining the environment of turbid or colored solutions, in which it is almost impossible to notice a change in the color of conventional acid-base indicators, use fluorescent indicators... They glow (fluoresce) in a different color depending on the pH of the solution. It is important that the glow of the indicator does not depend on the transparency and the intrinsic color of the solution. (5)
Natural indicators
If there are no real chemical indicators, then homemade indicators from natural raw materials can be successfully used to determine the medium of solutions.
The starting material can be geranium flowers, peony or mallow petals, iris, dark tulips or pansies, as well as raspberries, blueberries, chokeberries, cherry juices, currants, grapes, buckthorn and bird cherry fruits.
These natural indicators contain colored substances that can change their color in response to a particular stimulus. And, getting into an acidic or alkaline environment, they visually signal this. (6)
While on vacation in summer, you can dry flower petals and berries, from which you can prepare solutions as needed, and thus provide yourself with indicators.
Method of manufacturing indicators from natural raw materials
For research work, I used dried mallow petals, raspberries, black chokeberries, strawberries, buckthorn bark, red cabbage.
To prepare herbal indicators, I took 50 g of raw materials each, grinded, poured 200 ml of water and boiled for 1-2 minutes. The resulting decoctions were cooled and filtered. In order to prevent spoilage, alcohol was added to the resulting filtrate in a 2: 1 ratio. (8)
Having obtained the indicator solutions in this way, I checked what color they have in different environments.
I took a few drops of a homemade indicator with a pipette and added them one by one to an acidic or alkaline solution. The results of all these experiments were recorded in a table.
Table 1. Change in color of natural indicators in various environments.
Raw materials for cooking indicator | Natural indicator color | Coloring in sour environment | Coloring in alkaline environment |
Raspberries | Brown | Brown | Dark brown |
Chokeberry berries | Red brown | Pale pink | Dark green |
Strawberries | Red-orange | Orange | Dark yellow |
Buckthorn bark | Dark yellow |
||
Red cabbage | Blue violet | ||
Mallow petals | Dark green |
Determination of the medium of solutions of dishwashing detergents using vegetable indicators
In biology lessons, I learned that the outer surface of the epidermis is covered with a microscopically thin layer - an acid mantle.
Many biochemical processes take place in the epidermis. As a result, acids are formed - lactic, citric and others. Plus to this: sebum and sweat. All this constitutes the acidic mantle of the skin. Therefore, normal skin is acidic, with skin pH averaging 5.5. (2)
When using alkaline dishwashing detergents, we disrupt the normal acidic environment of the skin of the hands.
To protect the skin of the hands from negative effects, dish detergents should have a pH value corresponding to the pH value of the acid mantle of the epidermis.
With the help of prepared solutions of natural indicators, I checked what kind of environment different dish detergents have.
Table 2. Reaction of the medium of solutions of dishwashing detergents.
Conclusion
After conducting research work, I came to the following conclusions:
Many natural plants possess the properties of acid-base indicators, capable of changing their color depending on the environment in which they fall;
For the manufacture of solutions of plant indicators, you can use the following natural raw materials: raspberries, strawberries, black chokeberries, buckthorn bark, mallow petals, red cabbage;
Herbal indicator solutions can be used as acid-base indicators for determining the medium of dishwashing detergent solutions at home;
Detergents for dishes "Myth", "Fairy", "AOS" have an alkaline and slightly alkaline environment and when using them, rubber gloves must be used to protect the skin of the hands from negative effects, since the alkaline environment destroys the acid mantle of the epidermis;
Self-made indicators from natural raw materials can be used in chemistry lessons in rural schools, if there is a problem of providing the school with chemical indicators.
Bibliography
Alikberova L.Yu. Entertaining chemistry. - M .: AST-PRESS, 2002.
Alikberova L.Yu. Entertaining chemistry. A book for students, teachers and parents. - M .: AST-PRESS, 1999.
Hovhannisyan E.T. A guide to chemistry for university applicants. - M .: Higher school, 1998.
Savina L.A. I get to know the world. Children's encyclopedia. Chemistry. - M .: AST, 1996.
New encyclopedic dictionary. - M .: Great Russian Encyclopedia. Rinol Classic, 2000.
Encyclopedic Dictionary of a Young Chemist. - M .: Pedagogy, 1982.
Stepin B.D., Alikberova L.Yu. Entertaining tasks and spectacular chemistry experiments. - M .: Bustard, 2002.
Internet resources.
Application
Plants are natural indicators
Buckthorn mallow flower
Chokeberry Raspberry
MOU "Bersenevskaya secondary school". Supervisor: ,
Chemical and natural indicators are of great importance, since it is very important to know the pH - the environment in any biological and chemical process. For example, to grow plants, to obtain baking soda or detergent, a certain acidic or alkaline environment is needed. In the body of animals and humans, blood and gastric juice has a constant pH, and when it changes, the vital processes are disrupted. Indicator research helps regulate the pH value.
In chemical laboratories, including school ones, there are many different types and types of indicators. We all know litmus, methyl orange, phenolphthalein and others. In addition to chemical indicators, there are biological ones.
Target of this research work - to learn how to prepare extracts of indicators from plants in our area and apply them in practice.
Work tasks:
1. Get acquainted with the history of the discovery of some acid-base indicators.
2. Consider the principle of biological indication using the examples of algae, mosses, lichens, higher plants and get acquainted with the bioindicators of the hydrosphere, atmosphere, acidity and chemical composition of soils.
3. To study the method of preparation of natural indicators.
4. Experimentally investigate the possibility of using natural indicators to determine the environment of household solutions (soap, shampoo, washing powder, tea, soil extract.)
5. Improve experimental skills and abilities.
Research objects:
1. Natural substances that can be used to prepare acid-base indicators: juices of brightly colored fruits and berries, cell juice of flower petals of different plants.
2. Solutions of substances that are used in everyday life (tea), soil extract from the school experimental site.
In this research work, the history of the discovery of some indicators, their classification is studied, the principle of biological indication is considered on the examples of algae, mosses, lichens, higher plants. During the work, natural indicators were prepared and the possibility of using natural indicators to determine the environment of some household solutions (soap, shampoo, washing powder, tea, soil extract.) Was experimentally investigated.
As a result of the analysis of the obtained results of the work, the following conclusions were made:
Detergents for dishes "Myth", "Fairy", "AOS", "Pril", have an alkaline and slightly alkaline environment, therefore, when using them, it is necessary to use rubber gloves to protect the skin of the hands from negative effects, since the alkaline environment destroys the acid mantle of the epidermis ;
Dove soap and Children's shampoo have a neutral environment, so they can be used for delicate baby skin;
Clean Line soap should not be used by people with dry skin, since this type of soap, having an alkaline reaction of the environment, will dry the skin;
The washing powder "Lotos" taken for research has pronounced basic properties, so you need to work with it carefully. It is better not to wash woolen and silk items in this powder.
The variety of tea "May tea, fruit" has an acidic environment, so people with high acidity of the stomach should not drink it.
The soil taken for research from the school experimental plot has acidic properties, therefore, work should be carried out on liming it, since acidic soil adversely affects the development of plants.
As a result of research, we have made sure that natural indicators surround us everywhere and are always at hand. They determine both the pH environment of chemical and biological processes and the state of our planet as a whole.
The study of indicator plants is an interesting and rewarding topic. Moreover, it is not always possible to buy or order expensive indicators, and it is not at all difficult to prepare it yourself. Natural indicators from natural raw materials can be used in chemistry lessons in schools, if there is a problem of providing the school with chemical indicators, in the classes of elective and elective courses.
Perhaps the development of research in this direction will help bring our planet out of the ecological crisis and, to some extent, improve its ecological state.
The work took the second place in the regional competition "First steps", the third place - in the republican competition "Intellectual future of Mordovia"
Research work posted on the school website: http: // www. bersen. *****